93.
Goldeneye
(Martin Campbell, 1995)
Pierce may not be the best Bond but this is a tour-de-force of Bond-isms and Brosnan fills the role neatly. Sean Bean makes one of the best villians, the tank is one of the best Bond cars and the general dark tone of this one makes it stick out above the rest.
Interesting list, Pyro! I've not seen many that you mention, but I admit I haven't seen enough films from around the world. I hope to rectify that.
The mentions of Buffy and Firefly/Serenity are also very cool. Have you seen Dr. Horrible yet?
You write great little captions under your pics. I look forward to the next installment!