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So many moments in John Hughes films as well as John Carpenter films. John Williams in pretty much every movie he ever touched. Silvestri composing every Zemeckis film. Pino Dinaggio scoring De Palma's best and Joe Dante's early work. The score from Blood Simple is absolutely incredible. I have a tough time picking out just one scene. The score in Lucas is incredible. Basically all these movies have so many scenes where the music compliments, and they are almost all equally great in my opinion.
Tangerine Dreams score on Legend is incredible. The first scene where Mia Sara is scene in the forest is as good as it gets as far as fantasy is concerned.